Issued to . . . . . . . . . . : Allmetal, Inc.
P.O.Box 850
Bensenville, IL 60106
Attention: . . . . . . . . . : Material Safety Data Sheet Coordinator
The attached Material Safety Data Sheet relates potential hazards and
recommended practices for safe handling of the product that you purchased
from Raabe Corporation.
We urge you and your employees to review the entire MSDS prior to
handling, use or disposal of the product.
You are required to keep this MSDS on file for reference by company
employees or government regulatory officials.
If you resell or distribute this product, you must furnish a copy of the
MSDS to your customer.
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SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
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CHEMICAL PRODUCT IDENTIFICATION:
PRODUCT CODE. . . . : 63700 660489 .3M
PRODUCT NAME . . . : BLACK 216280
PRODUCT CLASS . . . : Touch-Up Paint Pen
MSDS PREPARATION DATE : 06/30/2005
MANUFACTURER IDENTIFICATION: CUSTOMER IDENTIFICATION:
RAABE COMPANY LLC Allmetal, Inc.
PO BOX 1090 P.O.Box 850
MENOMONEE FALLS WI 53052 Bensenville, IL 60106
EMERGENCY TELEPHONE NUMBERS:
24 HOURS A DAY - CALL CHEMTREC : 800-424-9300
INTERNATIONAL CALLS TO CHEMTREC : 703-527-3887
8 AM TO 4:30 PM CENTRAL TIME : 262-255-9500
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SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS
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1 ETHYLBENZENE
CAS# 100-41-4
ETHYLBENZENE
PCT BY WT: .7570 VAPOR PRESSURE: 19.000 MMHG @ 68F LEL 1.20
EXPOSURE LIMIT:
ACGIH TLV-TWA 100 ppm
ACGIH TLV-STEL 125 ppm
OSHA PEL-TWA 100 ppm
OSHA PEL-STEL 125 ppm
OTHER IARC (2B), CALIFORNIA PROP 65 (6/11/04)
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2 AMORPHOUS PRECIPITATED SILICA
CAS# 112926-00-8
AMORPHOUS PRECIPITATED SILICA
PCT BY WT: 1.0000
EXPOSURE LIMIT:
ACGIH TLV-TWA 10 mg/m3
ACGIH TLV-STEL NO INFO
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3 XYLENE
CAS# 1330-20-7
XYLENE
PCT BY WT: 4.0000 VAPOR PRESSURE: 6.600 MMHG @ 68F LEL 1.00
EXPOSURE LIMIT:
ACGIH TLV-TWA 100 ppm
ACGIH TLV-STEL 150 ppm
OSHA PEL-TWA 100 ppm
OSHA PEL-STEL 150 ppm
COMPANY N.E.
LD50(ORAL) 4300 mg/kg
LD50(DERMAL) 1700 mg/kg
LC50 18892 mg/m3
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4 Carbon Black
CAS# 1333-86-4
Carbon Black
PCT BY WT: 1.5660
EXPOSURE LIMIT:
ACGIH TLV-TWA 3.5 mg/m3
OSHA PEL-TWA 3.5 mg/m3
OTHER IARC (2B)
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5 ACETONE
CAS# 67-64-1
ACETONE
PCT BY WT: 15.0000 VAPOR PRESSURE: 231.000 MMHG @ 68F LEL 2.60
EXPOSURE LIMIT:
ACGIH TLV-TWA 750 ppm
ACGIH TLV-STEL 1000 ppm
OSHA PEL-TWA 750 ppm
OSHA PEL-STEL 1000 ppm
COMPANY N.E.
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6 METHYL ETHYL KETONE
CAS# 78-93-3
METHYL ETHYL KETONE
PCT BY WT: 13.0000 VAPOR PRESSURE: 85.000 MMHG @ 68F LEL 1.80
EXPOSURE LIMIT:
ACGIH TLV-TWA 200 ppm
ACGIH TLV-STEL 300 ppm
OSHA PEL-TWA 200 ppm
COMPANY N.E.
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7 GLYCOL ETHER PM ACETATE
CAS# 108-65-6
PROPYLENE GLYCOL METHYL ETHER ACETATE
PCT BY WT: 17.0000 VAPOR PRESSURE: 3.700 MMHG @ 68F LEL 1.30
EXPOSURE LIMIT:
ACGIH TLV-TWA NOT ESTABLISHED
ACGIH TLV-STEL NOT ESTABLISHED
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8 TOLUENE
CAS# 108-88-3
TOLUENE
PCT BY WT: 24.0000 VAPOR PRESSURE: 38.000 MMHG @ 68F LEL 1.40
EXPOSURE LIMIT:
ACGIH TLV-TWA 50 ppm
ACGIH TLV-STEL NO INFO
OSHA PEL-TWA 50 ppm
COMPANY N.E.
OTHER CALIFORNIA PROP 65 (1/01/91)
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This product contains one or more reported carcinogens or suspected
carcinogens which are noted NTP, IARC, or OSHA-Z in the other limits
recommended column.
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This substance is classified as a hazardous air pollutant.
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SECTION 3 - HAZARDS IDENTIFICATION
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EMERGENCY OVERVIEW:
Harmful if swallowed.
Harmful if inhaled.
Causes eye irritation.
Causes skin irritation.
Vapors irritating to eyes and respiratory tract.
Extremely flammable liquid and vapor.
Vapors may cause flash fire or explosion.
EYE:
May cause severe corneal injury if liquid comes in contact with the eyes.
SKIN:
May cause skin irritation.
Prolonged or repeated contact can result in defatting and drying of the
skin which may result in skin irritation and dermatitis (rash).
Harmful if absorbed through the skin.
Skin contact may aggravate an existing dermatitis.
INHALATION:
Exposure to high concentrations of vapors may cause dizziness, breathing
difficulty, headaches or respiratory irritation.
Extremely high concentrations may cause drowsiness, staggering,
confusion, unconsciousness, coma or death.
Excessive inhalation of vapors can cause nasal and respiratory
irritation.
Liquid or vapor may be irritating to skin, eyes, throat or lungs.
Prolonged inhalation of dusts containing free silica may result in the
development of a disabling pulmonary fibrosis(lung disease) known as
silicosis.
Intentional misuse by deliberately concentrating and inhaling the
contents of this product can be harmful or fatal.
Respiratory symptoms associated with pre-existing lung disorders may be
aggravated by exposure to material(s) is this product.
INGESTION:
Moderately toxic. May cause stomach discomfort, nausea, vomiting,
diarrhea, and narcosis.
Aspiration of material into the lungs if swallowed or if vomiting occurs
can cause chemical pneumonitis which can be fatal.
CHRONIC EFFECTS:
Chronic overexposure to a component or components in this material has
been found to cause the following effects in laboratory animals:
Kidney damage
Eye damage
Blood damage
Lung damage
Liver damage
Spleen damage
Anemia
Brain damage
Reproductive system damage
Chronic overexposure to a component or components is this product has
been suggested as a cause of the following effects in humans:
Liver damage
Cardiac abnormalities
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
Repeated breathing or skin contact of methyl ethyl ketone may increase
the potency of neurotoxins such as hexane if exposures occur at the same
time.
Central nervous system depression, shock, coma, visual disturbances, and
death. Onset of symptoms may be delayed as long as 30 hours.
2-Butoxyethanol causes harm to the fetus in laboratory animal studies.
Harm to the fetus occurs only at exposure levels that harm the pregnant
animal. The relevance of these findings to humans is uncertain.
There is evidence that repeated long-term exposure to vapor
concentrations greater than 50 ppm of n-butyl alcohol may result in some
hearing loss.
Product contains toluene which may be harmful to the fetus based on
animal studies.
Repeated exposure to toluene has been associated with high frequency
hearing loss in laboratory animals. The human consequences of this
finding is uncertain.
In April 1996, The International Agency for Research on Cancer (IARC)
published Monograph 65 which reclassifies Carbon Black into Group 2B
(possibly carcinogenic to humans).
In February 2000 the International Agency for Research on Cancer (IARC)
classified ethylbenzene as possibly carcinogenic to humans (Group 2B) on
the basis of sufficient evidence for carcinogenicity in experimental
animals but inadequate evidence for cancer in humans.
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SECTION 4 - FIRST AID MEASURES
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EYE CONTACT:
Immediately flush eyes with plenty of water. Get medical attention, if
irritation persists.
Flush with large quantities of water for 15 minutes.
SKIN CONTACT:
Wash thoroughly with soap and water and seek medical attention if
irritation persists. Remove contaminated clothing. Launder contaminated
clothing before reuse.
INHALATION:
For inhalation overexposure move person to fresh air. If breathing
stops, apply artificial respiration and seek medical attention.
INGESTION:
Since this product may contain materials which can cause lung damage if
aspirated into the lungs, the decision whether to induce vomiting or not
must be made by a physician after careful consideration of all materials
ingested.
Ingestion of large quantities of this material will result in methanol
poisoning. In this case treatment should include hemodialysis; the
administration of ethanol to interfere with the metabolism of methanol
and the administration of sodium carbonate to correct acidosis.
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SECTION 5 - FIRE FIGHTING MEASURES
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FIRE AND EXPLOSIVE PROPERTIES OF THE PRODUCT:
Flashpoint . . . . . . . . . . . . . : 1.0 øF
Explosion Level . . . . . . . . . . . : Low (LEL) - 1.0
High (UEL)- 13.1
EXTINGUISHING MEDIA:
Use Dry Chemical, Carbon Dioxide or Chemical Foam.
FIRE-FIGHTING PROCEDURES AND EQUIPMENT:
Keep containers tightly closed. Isolate from heat, sparks, and open
flame. Closed containers may explode when exposed to extreme heat.
Product vapors are heavier than air and may travel a long distance to a
source of ignition and flash back.
Full protective equipment including self-contained breathing apparatus to
avoid inhalation of vapors should be used.
Water spray should not be used except to keep down vapors or cool closed
containers to prevent build-up of pressure. If water is used, fog
nozzles are preferred.
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SECTION 6 - ACCIDENTAL RELEASE MEASURES
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CLEAN-UP AND CONTAINMENT:
Remove all sources of ignition. Avoid heat, sparks, flames and anything
which could cause fire.
Ventilate area of spill and adjacent low lying areas. Avoid breathing
solvent vapors. Remove with inert absorbent materials and non-sparking
tools.
Use water spray to disperse vapors. Minimize breathing gases, vapor,
fumes or decomposition products. Use self-contained breathing apparatus
with full face piece operated in positive pressure mode as needed.
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SECTION 7 - HANDLING AND STORAGE
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HANDLING:
Wash hands thoroughly after handling.
This product contains chemical(s) which are listed on California's
proposition 65 list. If the product is to be sold or used in California
a clear and reasonable warning must be provided such as:
Warning! This product contains a chemical or chemicals known to the State
of California to cause cancer.
STORAGE:
Store in a cool dry area with ventilation suitable for storing materials
shown in section 2.
Keep away from heat, sparks and flame.
Store in a cool place away from direct sunlight or any source of
ignition. Do not store at temperatures above 120 degrees F.
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SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
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ENGINEERING CONTROLS:
Sufficient ventilation, in volume and pattern, should be provided to keep
air contamination below current applicable OSHA permissible exposure
limit or ACGIH's TLV limit.
RESPIRATORY PROTECTION:
If workplace exposure limits are exceeded for any component(see section
2 for hazardous components and exposure limits), a NIOSH/OSHA approved
respirator suitable for components listed is recommended.
SKIN PROTECTION:
Chemical resistant plastic or rubber gloves recommended for prolonged or
repeated contact.
EYE PROTECTION:
Chemical goggles with side shields or face shield recommended if contact
with the eyes is likely.
OTHER PROTECTIVE EQUIPMENT:
Appropriate impervious clothing is recommended if prolonged or repeated
contact is likely.
HYGIENIC PRACTICES:
Wash hands before eating or smoking. Smoke in designated areas only.
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SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
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Vapor Pressure . . . . . . . . . . . : 231.00 mm Hg @ 20 C
Vapor Density . . . . . . . . . . . . : 3.70
Boiling Range . . . . . . . . . . . . : Lower - 133.0 øF
Higher - 999.0 øF
Specific Gravity . . . . . . . . . . : .927
Formula Weight per Volume . . . . . . : 7.7198 LB/GL
VOC (Calculated, LB/GAL) . . . . . . : 5.970
VOC (Calculated, GM/L). . . . . . . . : 715.38
Percent Volatile by Weight. . . . . . : 74.0250
Percent Volatile by Volume . . . . . : 79.8866
Evaporation Rate . . . . . . . . . . : 7.700 (n-Butyl Acetate = 1)
Viscosity . . . . . . . . . . . . . . : -N/A
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SECTION 10 - STABILITY AND REACTIVITY
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CONDITIONS TO AVOID:
Avoid contact with heat, sparks, and open flame.
INCOMPATIBILITIES:
Strong oxidizing agents.
DECOMPOSITION:
Thermal decomposition may produce carbon dioxide, carbon monoxide, and
unidentifiable organic materials.
POLYMERIZATION:
No hazardous polymerization will occur under normal conditions.
STABILITY:
The product is stable under normal storage conditions.
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SECTION 11 - TOXICOLOGICAL INFORMATION
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No specific information is available. Please refer to Section 2 and 3
for available information on exposure limits and hazards identification.
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SECTION 12 - ECOLOGICAL INFORMATION
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No specific ecological information is available for this product.
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SECTION 13 - DISPOSAL CONSIDERATIONS
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WASTE DISPOSAL:
Place in closed containers. Dispose of product in accordance with local,
county, state, and federal regulations.
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SECTION 14 - TRANSPORT INFORMATION
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Ground shipment of limited or excepted quantities of aerosols or liquid
paint in containers of 1 quart or less:
CONSUMER COMMODITY, ORM-D
Ground shipment of liquid paint in containers more than 1 quart:
PAINT, FLAMMABLE LIQUID, UN1263, CLASS 3, GROUP II
(Regulatory sources: DOT 49CFR 172.101)
Air shipment of limited or excepted quantities of aerosols or liquid paint
in containers of 1 quart or less:
CONSUMER COMMODITY, ID 8000, CLASS 9 MISCELLANEOUS LABEL
(Regulatory sources: ATAI Quantity Exemptions - Table 2.8.4, 2.7.A,
2.7.5, Packaging Instruction: 910)
OR
AEROSOLS, FLAMMABLE, UN1950, CLASS 2.1 LABEL
(Regulatory sources: ATAI Quantity Exemptions - Table 2.8.1, 2.8.4,
Packaging Instruction: Y203)
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SECTION 15 - REGULATORY INFORMATION
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SARA 313 INFORMATION:
This product contains the following substances subject to the
reporting requirements of Section 313 of Title III of the Superfund
Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
ETHYLBENZENE
CAS# 100-41-4 PCT BY WT: .7570
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XYLENE
CAS# 1330-20-7 PCT BY WT: 3.5490
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TOLUENE
CAS# 108-88-3 PCT BY WT: 23.5450
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FEDERAL REGULATIONS:
TOXIC SUBSTANCES CONTROL ACT: The chemical substances in this product are
listed on the TSCA Section 8 inventory.
STATE REGULATIONS:
This product contains chemical(s) which are listed on California's
proposition 65 list. If the product is to be sold or used in California
a clear and reasonable warning must be provided such as:
Warning! This product contains a chemical or chemicals known to the State
of California to cause cancer.
Warning! This product contains a chemical or chemicals known to the
State of California to cause birth defects or other reproductive harm.
Carbon Black requires a Prop 65 warning only if it is in the form of
airbourne, unbound, respirable particles.
NEW JERSEY RIGHT-TO-KNOW
The following non-hazardous ingredients are among the top five
components in this product
--------------------- CHEMICAL NAME --------------------- CAS NUMBER
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PENNSYLVANIA RIGHT-TO-KNOW
The following non-hazardous ingredients are present in the product at
greater than 3 %
--------------------- CHEMICAL NAME --------------------- CAS NUMBER
Acrylic Polymer Not Listed
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INTERNATIONAL REGULATIONS:
CANADA: The chemical substances in this product are listed on the
Canadian Domestic Substances List.
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SECTION 16 - OTHER INFORMATION
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The information contained on this MSDS is believed to be reliable and
accurate. Due to the changing nature of government information, it is
impossible to guarantee the accuracy of the information contained herein.
Since the conditions of handling and use are beyond our control, we make
no guarantee of results and assume no liability for damages incurred by
the use of this material. This information should not be regarded as
legal advice or regulation. It is the responsibility of the user to
comply with all Federal, State, and Local laws and regulations. For
questions relating to specific aspects of the requirements and regulations
consult the proper regulatory agency.
HMIS RATINGS:
HEALTH: 2* FLAMMABILITY: 3 REACTIVITY: 0 PERSONAL PROTECTION: B